One of the first scientists to suggest the existence of surface charge and surface charge density was a German physicist named, Hermann von Helmholtz.
After becoming a physics professor, he started making discoveries and writing theorems.
Believe it or not, when Hermann Von Helmholtz began his work and started publishing theories on electrodynamics in 1870, scientists had yet to accept one electrical theory.
Everyone was still shooting for the moon, taking guesses about how all this worked.
Maxwell, F. E. Neuman, and Weber were all competing in the game of discovering how electrodynamics worked.
Helmholtz was the first to develop agreed-upon formulas for electrodynamics.
The work of these early physicists paved the way for our current understanding of electricity and how it interacts with the surfaces around us.
It has allowed us to harness the power and make it work for us.
Because of this early work we are now able to determine these values with preconstructed formulas.